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Natural polymers

Learning from nature to build the next generation of sustainable materials

By 

  • Jun Wang, Ph.D., Co-founder and Co-chair, American Chemical Society (ACS) Green Chemistry Institute (GCI) Natural Polymers Consortium (NPC)

A hand runs a comb through liquid latex
Refining latex to create rubber, one of the most common natural polymers

© WWF / Dado Galdieri

The American Chemical Society (ACS) Green Chemistry Institute (GCI) Natural Polymers Consortium (NPC) is a group committed to exploring the utilization of natural polymers to accelerate the development of more sustainable functional materials. Launched in 2024 as a partnership between the ACS GCI and industry leaders, the Consortium envisions a future where natural polymers innovations can sustainably meet modern human needs.

Rethinking materials for a sustainable future

Modern society is built on polymers. They are found in packaging, textiles, transportation, electronics, healthcare products, and countless other applications that define everyday life. Synthetic plastics, in particular, have transformed the modern world by providing lightweight, durable, versatile, and affordable materials that can be engineered for nearly any purpose.

Yet as global demand for materials continues to grow, so does the need to ensure that material systems are compatible with long-term environmental sustainability. While improved recycling, reuse, and waste management remain essential, there is increasing interest in expanding the portfolio of available solutions. One promising opportunity lies in natural polymers, materials that nature has been producing, utilizing, and recycling for millions of years.

Natural polymers are not a new discovery. In fact, they are among the oldest materials used by humanity. What is new is our ability to understand, optimize, and deploy them using the tools of modern materials science, biotechnology, and artificial intelligence.

What are natural polymers?

To understand natural polymers, it is helpful to begin with a simple definition.

A polymer is a large molecule composed of many repeating building blocks called monomers. Synthetic polymers such as polyethylene, polypropylene, PET, and nylon are created through industrial chemical processes. Natural polymers, by contrast, are produced by living organisms.

Some of the most abundant natural polymers include:

  • Cellulose, the primary structural material in plants
  • Starch, the energy-storage polymer found in crops
  • Proteins such as silk and collagen
  • Natural rubber produced by latex-bearing plants
  • Chitin and chitosan found in fungi and crustaceans
  • Microbially synthesized materials such as polyhydroxyalkanoates (PHAs)
silk cocoons and spun silk in a basket
Silk from silkworm cocoons is an example of a natural polymer.

© shutterstock / kungfu01

These materials form the foundation of Earth's biological systems. Every year, nature produces and recycles enormous quantities of polymeric materials through highly efficient biological cycles. Unlike most conventional plastics, many natural polymers evolved alongside enzymes and organisms capable of breaking them down and returning their components to the environment.

Importantly, natural polymers should not be viewed as competitors to synthetic polymers. Both classes of materials have important roles to play. The real opportunity lies in understanding where each performs best and how they can be deployed responsibly within a more sustainable and circular materials economy.

Why do natural polymers matter?

The growing interest in natural polymers extends far beyond biodegradability.

Nature has spent billions of years refining molecular structures to perform highly specialized functions. Trees build strong and lightweight structures from cellulose. Silkworms produce fibers with extraordinary mechanical properties. Natural rubber delivers a unique combination of elasticity, toughness, and resilience that remains difficult to replicate synthetically.

These examples demonstrate that natural polymers are not inferior alternatives to synthetic materials. In many cases, they are sophisticated materials whose potential has only begun to be explored.

Another important consideration is the scale. Humanity produces approximately 450 million tons of plastic annually, enough for plastic pollution to reach even the most remote areas on earth, and yet this amount is dwarfed by the vast biological systems. The challenge, therefore, is not simply one of the material quantity. It is also about how effectively materials fit within existing cycles of production, use, recovery, and renewal.

Another important consideration is the scale. Humanity produces approximately 450 million tons of plastic annually, enough for plastic pollution to reach even the most remote areas on earth, and yet this amount is dwarfed by the vast biological systems. The challenge, therefore, is not simply one of the material quantity. It is also about how effectively materials fit within existing cycles of production, use, recovery, and renewal.

Natural polymers offer an opportunity to learn from and potentially leverage those biological cycles in appropriate applications.

Natural polymers are not inferior alternatives to synthetic materials. In many cases, they are sophisticated materials whose potential has only begun to be explored.

A new era of innovation

Ironically, more than a century of research on synthetic polymers may be one of the greatest enablers of future advances in natural polymers.

Throughout the twentieth century, scientists developed a deep understanding of polymer chemistry, structure-property relationships, processing technologies, and manufacturing systems. Today, that knowledge can be applied to a much broader universe of naturally-derived materials.

At the same time, emerging technologies are transforming our ability to study and engineer biological materials. Advanced analytical tools allow researchers to characterize complex molecular architectures with unprecedented precision. Biotechnology enables the production and modification of polymers through biological pathways. Artificial intelligence is helping scientists navigate the enormous structural complexity found in natural systems.

The success of AI-driven breakthroughs such as AlphaFold illustrates the power of learning from natural molecular design. By identifying patterns hidden within vast biological datasets, AI can accelerate discovery and help researchers develop new materials, enzymes, and manufacturing approaches inspired by nature.

This convergence of materials science, biology, and digital technologies has created a unique moment of opportunity for the natural polymer field.

The challenges must not be ignored

While the potential is exciting, natural polymers are not a universal solution.

Many challenges must still be addressed before widespread adoption can occur. Materials must deliver the performance, durability, safety, and functionality required by modern applications. Manufacturing processes must be scalable and economically viable. Supply chains must be reliable and sustainable. End-of-life pathways must be clearly understood.

A large mound of trash, composed largely of plastic
Sustainability cannot be assumed simply because a material originates from nature. The entire value chain must be considered, including end-of-life pathways.

© Yevhen Smyk / Pond5

In addition, sustainability cannot be assumed simply because a material originates from nature. Responsible innovation requires careful assessment of sourcing, land use, energy consumption, processing requirements, and environmental impacts across the entire value chain.

Addressing these challenges will require collaboration among scientists, engineers, manufacturers, policymakers, nongovernmental organizations, and investors.

Scaling the natural polymer opportunity

The encouraging news is that many of the foundations already exist.

Natural polymer feedstocks are produced around the world. Commercial products based on cellulose, natural rubber, starch, proteins, and microbial polymers already serve important markets. Advances in biotechnology, manufacturing, and digital tools continue to expand what is possible.

However, scaling natural polymers from niche applications to widespread adoption will require:

  • Continued scientific research and technological innovation
  • Investment in manufacturing capacity and infrastructure
  • Development of standards, testing methods, and best practices
  • Cross-sector dialogue throughout the value chain
  • Greater public understanding of the opportunities and limitations of natural polymers

Success will depend not on a single breakthrough, but on coordinated progress across science, industry, and society.

A call to action

The future of sustainable materials will not be defined by one material, one technology, or one organization. Instead, it will require a portfolio of solutions that include reduction, reuse, recycling, improved waste management, and the responsible development of alternative materials.

Natural polymers deserve a central place in that conversation.

Recognizing this opportunity, the American Chemical Society (ACS) Green Chemistry Institute (GCI) Natural Polymers Consortium (NPC) brings together stakeholders across the value chain to accelerate the sustainable development, production, and application of natural polymers as high-performance functional materials. The consortium seeks to bridge fundamental science and real-world implementation by advancing trusted science, developing guidance, and identifying practical pathways toward commercialization and adoption.

Natural polymers are not simply materials of the past. They represent an important part of the future. By combining nature's design principles with modern science and technology, we have an opportunity to create materials that better align with both human needs and the natural systems upon which we depend.

In the stories that follow, members of the ACS GCI NPC will share their experiences bringing natural polymers from research laboratories to commercial products. Together, these examples demonstrate that natural polymers are more than a promising idea. They are already becoming a reality.

For more information about NPC’s vision for advancing natural polymers as sustainable materials, read the publication Natural Polymers: Opportunities and Challenges in the Application and Commercialization as Sustainable Materials Amid Growing Environmental Awareness, which explores the opportunities, challenges, and actions needed to improve the performance, scalability, and sustainability of natural polymers and accelerate their commercialization for modern applications.